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Bis[2-(1H-benzimidazol-2-yl)phenolato]copper(II) dimethyl­formamide disolvate

✍ Scribed by Xi, Yun ;Li, Jun ;Zhang, Fengxing

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
130 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the title compound, [Cu(C 13 H 9 -N 2 O) 2 ]Á2C 3 H 7 NO, the Cu II ion is coordinated by two N and two O atoms from two deprotonated 2-(1H-benzimidazol-2yl)phenol ligands to give a four-coordinate distorted tetrahedral geometry. The Cu atom lies on a twofold rotation axis.

📜 SIMILAR VOLUMES

Bis[2-(2-oxidophen­yl)-1H-benzimidazole-
Bis[2-(2-oxidophen­yl)-1H-benzimidazole-κ2N3,O]zinc(II) dimethyl­formamide disolvate
✍ Zhao, Ya-Hui ;Su, Zhong-Min ;Wang, Yong ;Hao, Xiang-Rong ;Shao, Kui-Zhan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 156 KB

In the title compound, [Zn(C 13 H 9 N 2 O) 2 ]Á2C 3 H 7 NO, the Zn II ion is located on a twofold axis and chelated by two 2-(2hydroxyphenyl)benzimidazole ligands with a distorted tetrahedral geometry.

Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O
Bis[2-(benzimidazol-2-yl)phenolato-κ2N,O]cobalt(II)
✍ Bu, Huai-Yu ;Liu, Yong-Jun ;Liu, Qing-Fang ;Jia, Jing-Fen 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 139 KB

In the title compound, [Co(C 13 H 9 N 2 O) 2 ], the coordination geometry of the Co II atom is distorted tetrahedral; the Co atom lies on a twofold axis. Adjacent molecules are linked by N-HÁ Á ÁO hydrogen bonds into a three-dimensional network structure.