O-tetratin(IV) , [[(CH 3 ) 2 -SnO 2 CCHCl 2 ] 2 O] 2 , two Sn atoms are six-coordinate in a C 2 SnO 4 skew-trapezoidal bipyramidal geometry [CÐSnÐC 145.7 (4) ]. The other two Sn atoms are ®ve-coordinate [CÐ SnÐC 154.3 (4) ], but the geometry is better regarded as a trans-C 2 SnO 4 octahedron owing
Bis(1,1,3,3-tetramethyl-1,3-dibenzoatodistannoxane)
✍ Scribed by Amini, Mostafa M. ;Abadi, Shabnam Hossein ;Mirzaee, Mahdi ;Lügger, Thomas ;Hahn, F. Ekkehardt ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 293 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In centrosymmetric octamethyl-1 2 C,2 2 C,3 2 C,4 2 C-tetrakis-"-benzoato O H ;2:3 2 O;3:4 2 O,O H ;[[(CH 3 ) 2 SnO 2 CC 6 H 5 ] 2 O] 2 ; the exocyclic Sn atom is ®ve-coordinated and has a trans±C 3 SnO 2 trigonal bipyramidal geometry [CÐSnÐC = 139.4 (2) ] and the endocyclic Sn atom is six-coordinated and has a severely distorted trans-C 2 SnO 4 octahedral geometry [CÐSnÐC = 145.6 (2) ].
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.003 A Ê R factor = 0.029 wR factor = 0.077 Data-to-parameter ratio = 19.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the centrosymmetric title compound, [Co(C 11 H 9 N 2 O 4 ) 2 -(H 2 O) 4 ]Á0.5H 2 O, the Co II complex has a distorted octahedral coordination geometry with two monodentate ligands and four water molecules. The crystal packing is stabilized by intermolecular O-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds
The title compound, C 14 H 16 N 2 O 2 , was obtained from the reaction between S-tryptophan methyl ester hydrochloride and acetaldehyde. The molecule adopts a trans configuration, with the methyl and methoxycarbonyl groups located on opposite sides of the central tetrahydro--carboline unit. Bifurcat