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Bis­[1,1,3,3-tetra­methyl-1,3-bis­(di­chloro­acetato)­distannoxane]

✍ Scribed by Amini, Mostafa M. ;Abadi, Shabnam Hossein ;Mirzaee, Mahdi ;Yang, Shi-Yao ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
179 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

O-tetratin(IV)

, [[(CH 3 ) 2 -SnO 2 CCHCl 2 ] 2 O] 2 , two Sn atoms are six-coordinate in a C 2 SnO 4 skew-trapezoidal bipyramidal geometry [CÐSnÐC 145.7 (4) ]. The other two Sn atoms are ®ve-coordinate [CÐ SnÐC 154.3 (4) ], but the geometry is better regarded as a trans-C 2 SnO 4 octahedron owing to a long intermolecular SnÐ O bond [SnÐO 2.846 (6) A Ê ], which links the molecules into a linear chain.

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