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Bis(1 H -benzimidazole-κ N 3 )bis[2-(naphthalen-1-yl)acetato-κ 2O , O ′]nickel(II) monohydrate

✍ Scribed by Yin, Fu-Jun; Han, Li-Jun; Hong, Zhao; Xu, Xing-You; Ren, Li


Book ID
126599585
Publisher
International Union of Crystallography
Year
2012
Tongue
English
Weight
371 KB
Volume
68
Category
Article
ISSN
1600-5368

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The title compound, [Ni(C 13 H 7 Br 2 N 2 O) 2 ], an Ni II complex of the Schiff base 2-(3,5-dibromo-2-hydroxyphenyl)benzimidazole, was synthesized by the reaction of 3,5-dibromosalicylaldehyde and 1,2-phenylenediamine. The molecule resides on a twofold rotation axis. The Ni II atom exists in a dist

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In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.3