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Biosynthetic studies of marine lipids. 5. The biosynthesis of long-chain branched fatty acids in marine sponges

โœ Scribed by Carballeira, Nestor; Thompson, Janice E.; Ayanoglu, Eser; Djerassi, Carl


Book ID
126966523
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
903 KB
Volume
51
Category
Article
ISSN
0022-3263

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Biosynthetic studies of marine lipids 18
โœ Sohail Malik; Ivan L. Stoilov; Carl Djerassi ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 226 KB

Through appropriate labeling experiments, it was shown that the unusual sterol 3B-(hydroxymethyl)-A-nor-Sa-cholest-15-ene ( 1) is generated by ring contraction of dietary cholesterol followed by the introduction of the 15-16 double bond, rather than by ring contraction of 15-dehydrocholesterol (4).