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Biosynthetic origin and revised structure of ascochitine, a phytotoxic fungal metabolite. Incorporation of [1-13C]- and [1,2-13C2]-acetates and [Me-13C]methionine

โœ Scribed by Colombo, Lino; Gennari, Cesare; Ricca, Giuliana Severini; Scolastico, Carlo; Aragozzini, Fabrizio


Book ID
120345736
Publisher
Royal Society of Chemistry
Year
1980
Weight
191 KB
Category
Article
ISSN
1472-7781

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Biosynthetic studies with carbon-13: Inc
โœ Masato Tanabe; Kazuo T. Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 155 KB

We report the use of doubly labelled acetate and FT-'aC-NMR in the determination of the biosynthetic origin of ovalicin (1) (1) (graphinone),a sesquiterpene found in cultures of Pseudeurotium ovalis. The fungus was cultured in media fortified with 90% enriched 1,2-i3C-acetate that was diluted two-f