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Carbon-13 Fourier transform nuclear magnetic resonance spectroscopy. II. Pattern of biosynthetic incorporation of [1-13C]- and [2-13C]acetate into prodigiosin

โœ Scribed by Cushley, R. J.; Anderson, D. R.; Lipsky, S. R.; Sykes, R. J.; Wasserman, H. H.


Book ID
120601565
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
367 KB
Volume
93
Category
Article
ISSN
0002-7863

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Biosynthetic studies with carbon-13: Inc
โœ Masato Tanabe; Kazuo T. Suzuki ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 155 KB

We report the use of doubly labelled acetate and FT-'aC-NMR in the determination of the biosynthetic origin of ovalicin (1) (1) (graphinone),a sesquiterpene found in cultures of Pseudeurotium ovalis. The fungus was cultured in media fortified with 90% enriched 1,2-i3C-acetate that was diluted two-f