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Biosynthesis of deuterated benzylpenicillins I: Solvent deuterium oxide participation

✍ Scribed by Bruce C. Carlstedt; Henry L. Crespi; Martin I. Blake; Joseph J. Katz

Publisher
John Wiley and Sons
Year
1970
Tongue
English
Weight
657 KB
Volume
59
Category
Article
ISSN
0022-3549

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## Abstract Aromatic compounds bearing an __ortho__‐directing substituent may be deuterated by exchange with deuterium oxide in the presence of a range of cycloocta‐1,5‐dienyliridium(I)1,3‐dionate catalysts. The exchange takes place in several dipolar aprotic solvents and is directly applicable to