𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bioorganic and Medicinal Chemistry of Fluorine. Edited by Jean-Pierre Bégué and Danièle Bonnet-Delpon.

✍ Scribed by George B. Kauffman

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
303 KB
Volume
47
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

Ring-Opening of 1-CF3-Substituted Epoxy
Ring-Opening of 1-CF3-Substituted Epoxy Ethers with Carboxylic, Thiocarboxylic, and Phosphinic Acids in Basic Medium and in Hexafluoro-2-propanol
✍ Jernej Iskra; Danièle Bonnet-Delpon; Jean-Pierre Bégué 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 202 KB

Ring-opening of 1-CF 3 -substituted epoxy ethers with carboxylic acids was achieved in Et 3 N as solvent, and α-CF 3 -substituted acyloins and corresponding esters were obtained in good yields. In hexafluoro-2-propanol (HFIP) as solvent, the carboxylic acids acted as nucleophiles, and α-carbonyloxy