## Abstract Bergman cyclization of enediynes, regarded as a promising strategy for anticancer drugs, now finds its own niche in the area of polymer chemistry and material science. The highly reactive aromatic diradicals generated from Bergman cyclization can undergo polymerization acting as either
Biomimetic Principles in Polymer and Material Science
โ Scribed by Markus Antonietti; Peter Fratzl
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 305 KB
- Volume
- 211
- Category
- Article
- ISSN
- 1022-1352
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstract
โNot to copy Biology: to learn in modesty from her principles and to transfer it to materials space and conditions previously not accessible to biologyโ
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## Abstract The modification of polymers after the successful achievement of a polymerization process represents an important task in macromolecular science. Cycloaddition reactions, among them the metal catalyzed azide/alkyne โclickโ reaction (a variation of the Huisgen 1,3โdipolar cycloaddition r
the azide/alkyne-''click''reaction (also termed CuAAc) has had enormous impact within the field of polymer science. Thus, 220 original papers have been published in the context of click-chemistry and polymer science, more than 20 Reviews and at least 10 patents have appeared, altogether stressing th
## Abstract The metal catalyzed azide/alkyne โclickโ reaction (a variation of the Huisgen 1,3โdipolar cycloaddition reaction between terminal acetylenes and azides) has vastly increased in broadness and application in the field of polymer science. Thus, this reaction represents one of the few unive