𝔖 Bobbio Scriptorium
✦   LIBER   ✦

“Click”-Chemistry in Polymer and Material Science: the Update

✍ Scribed by Wolfgang H. Binder

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
43 KB
Volume
29
Category
Article
ISSN
1022-1336

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✦ Synopsis

the azide/alkyne-''click''reaction (also termed CuAAc) has had enormous impact within the field of polymer science. Thus, 220 original papers have been published in the context of click-chemistry and polymer science, more than 20 Reviews and at least 10 patents have appeared, altogether stressing the importance of this reaction. Given the short timeline for the discovery of Cu(I)-catalysis by Meldal et al. and Sharpless et al. in 2002 and the first published applications in polymer science ( 2004), someone can ask the question ''where does it stem from'', and -in the same line -find a quick answer: a high efficiency-reaction, coupled with a high functional group tolerance and solvent insensitivity (also highly active in water), working equally well under homogeneous and heterogeneous conditions certainly ranks

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