𝔖 Bobbio Scriptorium
✦   LIBER   ✦

‘Click’ Chemistry in Polymer and Material Science: An Update

✍ Scribed by Wolfgang H. Binder; Robert Sachsenhofer


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
900 KB
Volume
29
Category
Article
ISSN
1022-1336

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

The metal catalyzed azide/alkyne ‘click’ reaction (a variation of the Huisgen 1,3‐dipolar cycloaddition reaction between terminal acetylenes and azides) has vastly increased in broadness and application in the field of polymer science. Thus, this reaction represents one of the few universal, highly efficient functionalization reactions, which combines both high efficiency with an enormously high tolerance of functional groups and solvents under highly moderate reaction temperatures (25–70 °C). The present review assembles an update of this reaction in the field of polymer science (linear polymers, surfaces) with a focus on the synthesis of functionalized polymeric architectures and surfaces.

magnified image


📜 SIMILAR VOLUMES


“Click”-Chemistry in Polymer and Materia
✍ Wolfgang H. Binder 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 43 KB

the azide/alkyne-''click''reaction (also termed CuAAc) has had enormous impact within the field of polymer science. Thus, 220 original papers have been published in the context of click-chemistry and polymer science, more than 20 Reviews and at least 10 patents have appeared, altogether stressing th

‘Click’ Chemistry in Polymer and Materia
✍ Wolfgang H. Binder; Robert Sachsenhofer 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 816 KB

## Abstract The modification of polymers after the successful achievement of a polymerization process represents an important task in macromolecular science. Cycloaddition reactions, among them the metal catalyzed azide/alkyne ‘click’ reaction (a variation of the Huisgen 1,3‐dipolar cycloaddition r

Bergman Cyclization in Polymer Chemistry
✍ Yuli Xiao; Aiguo Hu 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 883 KB

## Abstract Bergman cyclization of enediynes, regarded as a promising strategy for anticancer drugs, now finds its own niche in the area of polymer chemistry and material science. The highly reactive aromatic diradicals generated from Bergman cyclization can undergo polymerization acting as either