Bidentate phosphinophenol ligand: synthesis and characterization of oxo and phenylimido rhenium(V) complexes of 2-diisopropylphosphinophenol
✍ Scribed by Frédérique Loiseau; Yolande Lucchese; Michèle Dartiguenave; Yvon Coulais
- Book ID
- 108427915
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 117 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0277-5387
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Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give