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Bicyclo[2.2.2]octane-2,5-carbolactone

✍ Scribed by Brecknell, DJ; Carman, RM; Day, PJ

Book ID
118172672
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1984
Tongue
English
Weight
697 KB
Volume
37
Category
Article
ISSN
0004-9425

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## Abstract The bromination of bicyclo[2.2.2]octadiene‐(2,5) (1) leads to a mixture of __trans__‐2,3‐dibromo‐bicyclo[2.2.2]octene‐(5) (9) and __trans__‐3,5‐dibromo‐homotricyclene (7a) in the ratio 7:3. This result is explained by __endo__ addition of bromine to (1) with formation of an intermediate