Bi-1,10-phenanthrolines and Their Mononuclear Ru(II) Complexes
✍ Scribed by Hu, Yi-Zhen; Xiang, Qin; Thummel, Randolph P.
- Book ID
- 121219280
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 90 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0020-1669
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📜 SIMILAR VOLUMES
## Abstract Friedländer reactions of 4‐aminoacridine‐3‐carbaldehyde with 1,3‐, 1,4‐di‐, and 1,3,5‐triacetylbenzenes afforded a series of corresponding (benzo[b]‐1,10‐phenanthrolin‐2‐yl)benzenes as new N,N,C‐polydentates. Reaction with 1,2‐diacetylbenzene afforded 1,2‐di(benzo[b]‐1,10‐phenanthrol‐2‐
A bis-chelating ligand (1), made of two 1,10-phenanthroline subunits connected with a p-(CH 2 ) 2 C 6 H 4 (CH 2 ) 2spacer through their 4 positions, has been prepared, using Skraup syntheses and reaction of the anion of 4-methyl-7anisyl-1,10-phenanthroline with α,α'-dibromo-p-xylene. Complexation of