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Between Ni(mnt) 2 and Ni(tfd) 2 Dithiolene Complexes: the Unsymmetrical 2-(Trifluoromethyl)acrylonitrile-1,2-dithiolate and Its Nickel Complexes

✍ Scribed by Jeannin, Olivier; Delaunay, Jacques; Barrière, Frédéric; Fourmigué, Marc


Book ID
127142122
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
427 KB
Volume
44
Category
Article
ISSN
0020-1669

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Synthesis and crystal structure of [Bu4N
✍ Yvonne S. J. Veldhuizen; Nora Veldman; Anthony L. Spek; Jaap G. Haasnoot; Jan Re 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 222 KB

## Abstract [Bu~4~N][Ni(mdt)~2~] (H~2~mdt = 2__H__‐1,3‐dithiole‐4,5‐dithiol) has been prepared in a three‐step synthesis from [Bu~4~N]~2~[Zn(dmit)~2~] (H~2~dmit = 2‐thione‐1,3‐dithiole‐4,5‐dithiol). The crystal structure is reported which shows that the Ni(mdt)~2~ anion is distorted significantly f