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Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity

โœ Scribed by Bonneau, Roland; Liu, Michael T. H.; Suresh, R. V.


Book ID
111693791
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
567 KB
Volume
93
Category
Article
ISSN
0022-3654

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Absolute rate constants for the reaction
โœ M.H. Begemann; R.W. Dreyfus; J.M. Jasinski ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 455 KB

Silylidyne, SiH, has been generated by excimer laser flash pbotolysis and its concentration monitored in real time by laserinduced fluorescence. Removal rates for SiH by hydrogen, deuterium and silane have been determined at 5 Torr total pressure in helium at ambient temperature. Silylidyne reacts g