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Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes

✍ Scribed by Liu, Michael T. H.; Bonneau, Roland

Book ID
127226969
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
240 KB
Volume
111
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Rate constants for the addition of the 2
Rate constants for the addition of the 2-cyano-2-propyl radical to alkenes in solution
✍ K. HΔ—berger; H. Fischer πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 811 KB

Absolute rate constants for the addition of the 2-cyano-2-propyl radical to 26 alkenes CH2 = CXY at 315 K were determined in solution by time-resolved electron-spin-resonance spectroscopy. They vary with the alkene substituents from 30 M-' s-l to 7'010 M-' s-'. For styrene the temperature dependence

Rate constants for the addition of the 2
Rate constants for the addition of the 2-hydroxy-2-propyl radical to alkenes in solution
✍ K. HΓ©berger; H. Fischer πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 432 KB πŸ‘ 1 views

Absolute rate constants for the addition of the 2-hydroxy-2-propyl radical to 18 substituted alkenes (CH2 = C X Y ) were determined at (296 -+ 1) Kin 2-propanol by time-resolved electronspin-resonance spectroscopy. With alkene substitution the rate constants vary by more than 6 orders of magnitude.