𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Benz­yl 5-bromo-4-methyl­salicylate

✍ Scribed by Fan, Ning-Juan ;Wei, Yi-Bin ;Pu, Xiao-Hua ;Guo, Wei

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
331 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, C 15 H 13 BrO 3 , was synthesized by the benzyl esterification of 5-bromo-4-methylsalicylic acid. The molecular conformation is stabilized by an intramolecular hydrogen bond.

📜 SIMILAR VOLUMES

Methyl 5-bromo­salicylate
Methyl 5-bromo­salicylate
✍ Xiao, Feng-Ping ;Li, Fen-Fang ;Jin, Long-Fei ;Wu, Yong-Fei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 230 KB

In the title compound, C 8 H 7 BrO 3 , an intramolecular hydrogen bond exists between the hydroxyl group and the O atom of the carbonyl group. The molecules are stacked along the b axis with weakinteractions.

N-(4-Bromo­benz­yl)phthalimide
N-(4-Bromo­benz­yl)phthalimide
✍ Chen, Ping ;Zhang, Ling ;Li, Dan 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB
4-Methyl­phen­yl benz­yl sulfone
4-Methyl­phen­yl benz­yl sulfone
✍ Li, Yong-Shu ;Su, Wei-Ke 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 134 KB

In the title compound, C 14 H 14 O 2 S, the dihedral angle between the two benzene rings is 15.5 (1) . In the crystal structure, an intermolecular C-HÁ Á ÁO interaction links the molecules into zigzag chains along the a axis.

3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl
3-Bromo-2-(4-bromo-2,5-dimethoxy­benz­yl)-1-phenyl­sulfon­yl-1H-indole
✍ Ravishankar, T. ;Chinnakali, K. ;Arumugam, N. ;Srinivasan, P. C. ;Usman, Anwar ; 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

In the title compound, C 23 H 19 Br 2 NO 4 S, the orientation of the phenylsulfonyl substituent with respect to the indole ring system is influenced by intramolecular C-HÁ Á ÁO interactions. The sulfonyl-bound phenyl ring is orthogonal to the indole ring system. In the crystal structure,stacking int