The title compound, C 15 H 13 BrO 3 , was synthesized by the benzyl esterification of 5-bromo-4-methylsalicylic acid. The molecular conformation is stabilized by an intramolecular hydrogen bond.
✦ LIBER ✦
Methyl 5-bromosalicylate
✍ Scribed by Xiao, Feng-Ping ;Li, Fen-Fang ;Jin, Long-Fei ;Wu, Yong-Fei
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 230 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, C 8 H 7 BrO 3 , an intramolecular hydrogen bond exists between the hydroxyl group and the O atom of the carbonyl group. The molecules are stacked along the b axis with weakinteractions.
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.051 wR factor = 0.133 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.