𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Benzeneselenolates of Mercury(II). Crystal and Molecular Structures of [Hg(SePh)2] and (Bu4N)[Hg(SePh)3]

✍ Scribed by Ernesto Schulz Lang; Marcelo Müller Dias; Ulrich Abram; Ezequiel M. Vázquez-López

Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
133 KB
Volume
626
Category
Article
ISSN
0372-7874

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of dibenzenediselenide, (SePh) 2 , with mercury in refluxing xylene gives bis(benzeneselenolato)mercury(II), [Hg(SePh) 2 ], in a good yield. ( n Bu 4 N)[Hg(SePh) 3 ] is obtained by the reaction of [Hg(SePh) 2 ] with a solution of [SePh] ± and ( n Bu 4 N)Br in ethanol. The solid state structures of both compounds have been determined by X-ray diffraction. The mercury atom in [Hg(SePh) 2 ] (space group C2, a = 7.428(2), b = 5.670(1), c = 14.796(4) A Ê , b = 103.60(1)°) is linearly co-ordinated by two selenium atoms (Hg±Se = 2.471(2) A Ê , Se±Hg±Se = 178.0(3)°). Additional weak interactions between the metal and selenium atoms of neighbouring molecules (Hg ´´´Se = 3.4±3.6 A Ê ) associate the [Hg(SePh) 2 ] units to layers. The crystal structure of ( n Bu 4 N)[Hg(SePh) 3 ] (space group P2 1 /c, a = 9.741(1), b = 17.334(1), c = 21.785(1) A Ê , b = 95.27( 5)°) consists of discrete complex anions and ( n Bu 4 N) + counter ions. The coordination geometry of mercury is distorted trigonal-planar with Hg±Se distances ranging between 2.5 and 2.6 A Ê .

📜 SIMILAR VOLUMES

Crystal and molecular structure of [Hg3(
Crystal and molecular structure of [Hg3(H2pdm)2(Hpdm) (μ-Cl)2Cl3]
✍ Norberto Farfán; Herbert Höpfl 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 196 KB 👁 1 views

The reaction between mercury(II)chloride and 2,6-pyridinedimethanol provides a molecule with the empirical formula [Hg 3 (H 2 pdm) 2 -(Hpdm) (l-Cl) 2 Cl 3 ], whose crystal and molecular structure has been studied: a ‫ס‬ 10.640(1), b ‫ס‬ 10.818(2), c ‫ס‬ 13.159(2) A ˚, ␣ ‫ס‬ 88.480(5), b ‫ס‬ 75.067(4

Synthesis and Crystal Structure of [(1-(
Synthesis and Crystal Structure of [(1-(Phenyltriazenido)-2-(phenyltriazeno)benzene)(nitrato)mercury(II)], {Hg[PhN3C6H4N3(H)Ph](NO3)}, a Complex with Weak Metal-Arene π-Interactions
✍ Manfredo Hörner; Adailton João Bortoluzzi; Johannes Beck; Michael Serafin 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 German ⚖ 102 KB 👁 1 views

The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ

Synthesis and Molecular and Crystal Stru
Synthesis and Molecular and Crystal Structure of a New Tricyclic B3N4S2Si2 System
✍ Dr. Carl Habben; Prof. Dr. Anton Meller; Dr. Mathias Noltemeyer; Prof. George M. 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 English ⚖ 331 KB

In the crystals of (2,5-DM-DCNQI)2Cu the copper ions are arranged in chains, each surrounded by four stacks of the dicyanoquinonediimine (Fig. 3).[13] An electronic con-Fig. 3. Perspective view of the crystal structure along the cam,: the chain of copper atoms is surrounded by four stacks of 2,s-DM-