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Preparation, Single Crystal Structure Analysis, and Thermal Behaviour of the Acidic Mercury(I) Phosphate (Hg2)2(H2PO4)(PO4)

✍ Scribed by Matthias Weil


Publisher
John Wiley and Sons
Year
2000
Tongue
German
Weight
114 KB
Volume
626
Category
Article
ISSN
0372-7874

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Single crystals of sodium iron hydrogen phosphate, NaFe(HPO 4 )(H 2 PO 4 ) 2 Β΄H2 O, were prepared hydrothermally by heating a mixture of Fe 2 O 3 , H 3 PO 4 and Na 2 CO 3 with a small amount of water. It crystallizes orthorhombic (Pbcn (NΒ°60), Z = 8, a = 872.91( 7), b = 1249.54(8), c = 1894.4(1) pm)