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Beckmann rearrangements in the bicyclo[2.2.1]heptan-2-one series

✍ Scribed by Peter A. Hunt; Christopher J. Moody


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
120 KB
Volume
30
Category
Article
ISSN
0040-4039

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The Lithium Amide Induced Rearrangement
✍ OdΓ³n Arjona; Roberto Menchaca; Joaquı́n Plumet πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 132 KB

AbstractÐLithium amides induce rearrangement of the title compounds 1 to afford nortricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observed reaction products.