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The Lithium Amide Induced Rearrangement of Epoxysulfones Derived from Bicyclo[2.2.1]heptane System

✍ Scribed by Odón Arjona; Roberto Menchaca; Joaquı́n Plumet

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 132 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00294-5

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✦ Synopsis

AbstractÐLithium amides induce rearrangement of the title compounds 1 to afford nortricyclanones 4 via a ketocarbene intermediate. Compounds 4 undergo hydride transfer reduction and imino aldol condensation to afford the other observed reaction products.

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