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ChemInform Abstract: The Lithium Amide Induced Rearrangement of Epoxysulfones Derived from Bicyclo[2.2.1]heptane System.

✍ Scribed by Odon Arjona; Roberto Menchaca; Joaquin Plumet

Publisher: John Wiley and Sons
Year: 2000
Weight: 30 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200039047

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Diquinane Synthesis Based on Anionic (1, 3) Sigmatropic Rearrangements of an Oxy-Cope System Incorporated in the Bicyclo(3.2.1)oct-6-ene Framework. -Treatment of 2-vinylbicyclooctenols (I) and (V) with KH in an appropriate solvent results in the formation of the (5-5) fused-ring compounds (II) and (