𝔖 Bobbio Scriptorium
✦   LIBER   ✦

BEBO calculations of kinetic isotope effects for methyl radical reactions with alkanes and ketones

✍ Scribed by Löser, U. ;Scherzer, K.

Book ID
112688887
Publisher
Springer
Year
1979
Tongue
English
Weight
165 KB
Volume
11
Category
Article
ISSN
0133-1736

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Kinetics studies of reactions of OH radi
Kinetics studies of reactions of OH radicals with four haloethanes part I. Experiment and BEBO calculation
✍ Shi-Ben Xing; Su-Hao Shi; Lian-Xiong Qiu 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 454 KB

## Abstract The rate constants for reactions of OH with ClCH~2~CH~2~Cl, Cl~2~CHCHCl~2~, BrCH~2~CH~2~Br, CH~3~CH~2~Br have been measured by using a discharge flow‐resonance fluorescence (DF‐RF) technique over the temperature range 293–418 K. The rate constants as a function of temperature were fitte

Reactions of methyl radicals with acetal
Reactions of methyl radicals with acetaldehyde and acetaldehyde-d1. II. BEBO calculations of the temperature dependence of the rate constants
✍ T. BéRces; F. MáRta 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 527 KB

The BEBO method was used to calculate the kinetic isotope effect for formyl-hydrogen abstraction from acetaldehyde by methyl radicals. The calculated isotope effect and experimental ratios of the rate constants obtained at 785'K for the reactions of CH3 with CHDCHO and CHDCDO, together with the theo