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Carbon Kinetic Isotope Effects in the Gas Phase Reactions of Light Alkanes and Ethene with the OH Radical at 296 ± 4 K

✍ Scribed by Anderson, Rebecca S.; Huang, Lin; Iannone, Richard; Thompson, Alexandra E.; Rudolph, Jochen


Book ID
126215990
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
85 KB
Volume
108
Category
Article
ISSN
1089-5639

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✍ Roger Atkinson; Sara M. Aschmann 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 444 KB 👁 1 views

Using a relative rate technique, rate constants for the gas-phase reactions of the OH radical with the three cresols and the six dimethylphenols have been determined a t 296 t 2 K and atmospheric pressure. The rate constants for the cresols, which range from 4.3 x lo-" cm3 molecule-' s-' to 6.8 x lo