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BCl3-Mediated Ene Reaction of Sulfur Dioxide and Unfunctionalized Alkenes

✍ Scribed by Dean Marković; Chandra M. R. Volla; Pierre Vogel; Adrián Varela-Álvarez; José A. Sordo


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
290 KB
Volume
16
Category
Article
ISSN
0947-6539

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From the standpoint of atom efficiency, [1] nucleophilic additions to alkenes or alcohols instead of alkyl halides are attractive salt-free methods (Scheme 1). Simple alkenes are readily accessible and abundant carbon-atom sources, but intermolecular additions of 1,3-dicarbonyl compounds to simple a