Basic reaction rate constants for oxidation of ethylbenzene by molecular oxygen
โ Scribed by V.F. Tzepalov; V.Ya. Shlyapeentokh
- Book ID
- 113172411
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 88 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0021-9517
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Reactions of HCCCO and NCCO radicals with O 2 have been studied by a combination of pulsed laser photolysis and photoionization mass spectrometry. HCCCO was produced by 193-nm photolysis of methylpropiolate or 3-butyn-2-one, and NCCO was formed by 193-nm photolysis of acetylcyanide. The rate constan
Rate constants have been measured for the reactions of four hydrocarbon radicals with O2 in the gas phase at room temperature. Laser flash photolysis was used to generate low concentrations of radicals. A photoionization mass spectrometer followed the radical loss as a function of time. The measured