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Rate constants for the reaction of singlet oxygen with diazocompounds

✍ Scribed by Korotaeva, N. M. ;Shereshovets, V. V. ;Komissarov, V. D.

Book ID
112706114
Publisher
Springer
Year
1992
Tongue
English
Weight
92 KB
Volume
48
Category
Article
ISSN
0133-1736

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Using the recently detected intense UV absorption spectrum of SiCl,(% 'A,) the absolute rate constant has been measured for its reaction with oxygen. The value of the bimolecular rate constant, k(SiCl,+O,), is equal to (3.4k0.7) x lo9 M-' s-' at 25Β°C.