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Base-Catalyzed Stereoselective Isomerization of Electron-Deficient Propargylic Alcohols to (E)-Enones.

✍ Scribed by John P. Sonye; Kazunori Koide


Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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Cationic Rhodium(I)/Bisphosphane Complex
✍ Ken Tanaka; Takeaki Shoji; Masao Hirano πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 270 KB

## Abstract We have determined that hydrogenated cationic Rh(I)/bisphosphane complexes are highly active catalysts for the isomerization of secondary propargylic alcohols to Ξ±,β‐enones. A kinetic resolution of secondary propargylic alcohols proceeded with moderate selectivity with [Rh((__R__)‐BINAP