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Base-catalysed prototropic rearrangement. Part I. Comparison of the base-catalysed and the metal carbonyl-catalysed isomerisation of allyl ethers

✍ Scribed by Hubert, A. J.; Georis, A.; Warin, R.; Teyssi�, P.

Book ID: 120976082
Publisher: Royal Society of Chemistry
Year: 1972
Tongue: English
Weight: 609 KB
Volume: 4
Category: Article
ISSN: 1472-779X
DOI: 10.1039/P29720000366

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Meth) l ,,ernolate ~s rearranged to methyl cor~olate by hthmna dJeth)lamlde at 0 C Jn about 60 "o y~eld Dehydration of th~s hydroxy ester yields a mixture of octadecatr~enoates By SMlllar reactions hnole~c ester has been con,mrted to racemlc corlohc ester and to racem~c dJmorphecohc ester, and hnole