𝔖 Bobbio Scriptorium
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Fatty acids, part 20: The base-catalysed rearrangement of vernolic and other epoxy esters: The partial synthesis of methyl coriolate, methyl dimorphecolate, and some conjugated polyenoic esters by a possible biosynthetic route

✍ Scribed by H.B.S. Conacher; F.D. Gunstone


Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
524 KB
Volume
3
Category
Article
ISSN
0009-3084

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✦ Synopsis


Meth) l ,,ernolate ~s rearranged to methyl cor~olate by hthmna dJeth)lamlde at 0 C Jn about 60 "o y~eld Dehydration of th~s hydroxy ester yields a mixture of octadecatr~enoates By SMlllar reactions hnole~c ester has been con,mrted to racemlc corlohc ester and to racem~c dJmorphecohc ester, and hnolemc e~ter to parmanc ester