𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Base catalysed rearrangements of 4-hydroxyphenyl allyl ethers: syntheses of alliodorin and alliodorol

✍ Scribed by Harwood, Laurence M.; Oxford, Anona J.; Thomson, Colin

Book ID
120987852
Publisher
The Royal Society of Chemistry
Year
1991
Tongue
English
Weight
262 KB
Volume
18
Category
Article
ISSN
0022-4936

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

1,3-ASYMMETRIC INDUCTION IN RETRO-[1,4]-
1,3-ASYMMETRIC INDUCTION IN RETRO-[1,4]-BROOK REARRANGEMENTS OF LITHIATED ALLYL METHYL ETHERS AND LITHIATED ALLYL MOM ETHERS
✍ Dirk Goeppel; Reinhard BrΓΌckner πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 281 KB

The tBrrPh\*Si-containing allyl methylether cis-2 and its trans isomerwere Iithiatedwith sBuLi at -78Β°C in THF. Thereupon,diastereoselectiveretro-[l,4]-Brook rearrangementsoccurred which furnishedthe allylsilanearrti,trans-5 with 86-87%diastereocontrol. The analogousallylMOM etherscis-and rrans-3 un