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Backside displacement in the unimolecular gas-phase decarboxylation of alkyl phenyl carbonate radical cations

✍ Scribed by Audier, Henri Edouard; Morton, Thomas Hellman


Book ID
127077385
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
407 KB
Volume
113
Category
Article
ISSN
0002-7863

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Unimolecular chemistry of oxazole and is
✍ R. Flammang; M. Plisnier; G. Bouchoux; Y. Hoppilliard; S. Humbert; C. Wentrup πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 837 KB

Molecular radical cations of oxazole (1) and isoxazole (2) dissociate by losing carbon monoxide or a hydrogen atom, respectively. These fragmentations were examined by use of tandem mass spectrometry, flash vacuum pyro- lysis and ab initiu molecular orbital calculations. A multi-step mechanism is pr