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Ion-radical complexes in the gas phase: structure and mechanism in the fragmentation of ionized alkyl phenyl ethers

✍ Scribed by Harnish, David; Holmes, John L.

Book ID
126768855
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
796 KB
Volume
113
Category
Article
ISSN
0002-7863

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## Abstract The mechanistic aspects of alkene loss from ionized ethyl‐and __n__‐propyl phenyl thioethers have been studied by use of deuterium labelling and tandem mass spectrometry. Loss of ethene from the molecular ion of ethyl phenyl thioether proceeds predominantly by a specific H‐shift from th