Unimolecular fragrmentations of the radical cation of the high-valent organometal oxide CH3ReO3 and its reactivity with ethylene in the gas phase

Reactivity of vinylamine radical cation

Reactivity of vinylamine radical cation with neutral olefins: An example of ‘ionic’ free-radical chemistry in the gas phase

✍ Guy Bouchoux; Florence Penaud-Berruyer 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 667 KB

Hydrogen atom abstraction and cycloaddition-cycloreversion reactions between ionized vinylamine and neutral olefins were studied in a Fourier transform ion cyclotron resonance spectrometer. The efficiencies of both processes are appreciably less than unity. The trend in reaction efficiencies is cons