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b1Σ+ Emissions from group V–VII diatomic molecules. b 0+ → X1 0+, X2 1 emissions of AsI and SbI

✍ Scribed by R. Winter; H. Kruse; E.H. Fink; J. Wildt; F. Zabel

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
499 KB
Volume
104
Category
Article
ISSN
0009-2614

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✦ Synopsis

Chemiluminescence from the b 0) * Xr O+ band system of Asl and of the b O+-+ Xt O*, X-J I systems of SbI in the near-infrared sPect.ral r&on has been observed in a discharge flow system. Analysis of the spectra led to the spectroscopic constants (In cm-') of AsI: wc(Xr, X,) = 257 -L 2, wexe(Xr, X,) = 0.82 = 02, T,(bO? = 11738 i 5, w&O+) = 271 f 2, weXe(bO?=O.66 t 0.2,and of SbI: Te(X2 1)=965 t 10, we(Xt, X2)=206 i 6, Te(bOc)= 12326 2 10,we(bO~= 211 2 6. Ihe intensity ratio of the two sub-systems b O*-Xa 1 and b O*+ X1 O+ was found to be ==0.

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