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b 1Σ+ Emissions from group V–VII diatomic molecules. b 0+→X10+, X2 1 band systems of AsCl and AsBr

✍ Scribed by H. Kruse; R. Winter; E.H. Fink; J. Wildt; F. Zabel

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
371 KB
Volume
111
Category
Article
ISSN
0009-2614

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✦ Synopsis

CJmnilumincsccnce of the lo O+ -XI 0". Xx J band spstclns of AsCl and .451)r in tllc near-infrared spectral region has been observed in a discharge-flow system. Analysis of the spectra Jcd IO rhe spcctrosc~pic constants (in cm-') for -4~0: w,fS1, X2) =424 2 6. T,(X2 1) = 140 -+_ 8, T,(bO*) = I2573 * JO, T,(X2J)=J93~8,T,(bO+)=1~313iJ0,w, w,(bO+j =443 i 8:and for AsBr: we(X1,Xz) = 316 16, (bO+) = 329 z 6. TJIC intensity ratio of the b -X2 and b -X1 sub+.ystcms %s found to be =I .4 for AsCJ and =0.05 for AsBr_

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