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b1Σ+ and a1Δ emissions from group VI-VI diatomic molecules: b0+ → X10+, x21 emissions of TeO and TeS

✍ Scribed by R. Winter; I. Barnes; E.H. Fink; J. Wildt; F. Zabel

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
424 KB
Volume
80
Category
Article
ISSN
0022-2860

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CJmnilumincsccnce of the lo O+ -XI 0". Xx J band spstclns of AsCl and .451)r in tllc near-infrared spectral region has been observed in a discharge-flow system. Analysis of the spectra Jcd IO rhe spcctrosc~pic constants (in cm-') for -4~0: w,fS1, X2) =424 2 6. T,(X2 1) = 140 -+\_ 8, T,(bO\*) = I2573

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Emission spectra of the a 1 ⌬(a2) 3 X 2 1 and b 1 ⌺ ϩ (b0 ϩ ) 3 X 3 ⌺ Ϫ (X 1 0 ϩ , X 2 1) transitions of SbF, SbCl, SbBr, and SbI have been observed in the near-infrared spectral region. The antimony halide radicals were generated and excited in a fast-flow system by reaction of antimony vapor (Sb x