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Aziridines IX. The isomerization of 1,2,3-triphenylaziridine

โœ Scribed by Harold W. Heine; Fred Scholer

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
101 KB
Volume
5
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Aziridines XI. Reaction of 1,2,3-triphen
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โœ Harold W. Heine; Richard Peavy ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 104 KB

A new reactibn involving carbon-carbon bond cleavage of the aziridine ring has been observed. Refluxing of 1, 2, J-triphenylaziridine(') (I) with diethylacetylene dicarboxylate in toluene for eleven hours forms 1,2,5-triphenyl-3,4-dicarbethoxy-3-pyrroline(II) in 98% vield. I Recrystallization from e

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Synthesis and thermal isomerization of cis N-methyl-2,3-divinyl aziridine.
โœ J.C. Pommelet; J. Chuche ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 128 KB

Until recently, all attemps to prepare cis-1,2-divinylcyclopropane & and cis N-alkyl-2,3\_divinylaziridines & 3 have failed, although cis-2,3-divinyloxirae I+ 4g5 has been isolated at room temperature. These three-membered rings L undergo the thermal Cope expansion to seven-membered dienes II \_.