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Synthesis of Chiral cis-1,2,3-Trisubstituted Aziridines

✍ Scribed by Tuyen Nguyen Van; Norbert De Kimpe


Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
156 KB
Volume
56
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES


Sterically congested chiral activated az
✍ Hiroaki Ohno; Ayako Toda; Nobutaka Fujii; Yoshihisa Miwa; Tooru Taga; Yumiko Yam πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 287 KB

Whereas treatment of the allylic mesylates of N-protected 2-alkyl-4-amino-(E)-2-alken-1-ols with sodium hydride in DMF yields exclusively the corresponding 2,3-trans-2-alkenyl-3-alkylazJridines, exposure of the methyl carbonates of N-protected 2-alkyl-4-amino-(E)-2-alken-l-ols to Pd(PPh3) 4 (5-20 mo