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ChemInform Abstract: Sterically Congested Chiral Activated Aziridines: Synthesis of Both 2,3-cis- and 2,3-trans-2-Alkenyl-3-alkylaziridines from Common Intermediates.

โœ Scribed by Hiroaki Ohno; Ayako Toda; Nobutaka Fujii; Yoshihisa Miwa; Tooru Taga; Yumiko Yamaoka; Eriko Osawa; Toshiro Ibuka


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Selective Synthesis
โœ Kiyonori Ishii; Hiroaki Ohno; Yoshiji Takemoto; Eriko Osawa; Yumiko Yamaoka; Nob ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 2 views

Selective Synthesis of cis-2-Vinyl-3-alkylaziridines and 3-Pyrrolines from Common Intermediates (Z)-4-N-Arylsulfonylaminoalk-2-en-1ols. -Both the title aziridines and pyrrolines are conveniently available from Z-aminoalkenols (I) by properly choosing the reaction conditions. Thus, palladium-catalyz