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ChemInform Abstract: Selective Synthesis of Nonracemic 3-Pyrrolines and 2,3-cis-2-Vinylaziridines from (Z)-Amino Allylic Alcohols: A New Synthetic Route to Chiral 3,4-Dehydroproline.

โœ Scribed by Kiyonori Ishii; Hiroaki Ohno; Yoshiji Takemoto; Toshiro Ibuka

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Selective Synthesis
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Selective Synthesis of cis-2-Vinyl-3-alkylaziridines and 3-Pyrrolines from Common Intermediates (Z)-4-N-Arylsulfonylaminoalk-2-en-1ols. -Both the title aziridines and pyrrolines are conveniently available from Z-aminoalkenols (I) by properly choosing the reaction conditions. Thus, palladium-catalyz

ChemInform Abstract: A Short, Multigram
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thiophenecarboxylate (III) and its conversion into novel ethylenic thiophenes (IX) is described. The antimicrobial activity of the prepared compounds is evaluated. Derivative (Va), the most active compound, shows remarkable antimicrobial activity on filamentous fungi.