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The photochemistry of 1,2,3-triphenylaziridine

โœ Scribed by H. Nozaki; S. Fujita; R. Noyori


Publisher
Elsevier Science
Year
1968
Tongue
French
Weight
393 KB
Volume
24
Category
Article
ISSN
0040-4020

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๐Ÿ“œ SIMILAR VOLUMES


Aziridines XI. Reaction of 1,2,3-triphen
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A new reactibn involving carbon-carbon bond cleavage of the aziridine ring has been observed. Refluxing of 1, 2, J-triphenylaziridine(') (I) with diethylacetylene dicarboxylate in toluene for eleven hours forms 1,2,5-triphenyl-3,4-dicarbethoxy-3-pyrroline(II) in 98% vield. I Recrystallization from e

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As with the symmetrical, acyclic vicinal-diones previously investigated', the photocyclizations of these substances give predominantly 2-hydroxycyclobutanones. Further mechanism studies have shown that the triplet state gives this reaction since it is photosensitized by benzophenone, and that with