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Azacycloalkanes. Part 37. 3,4-Dihydro-5H-pyrrolo[1,2-a]diazepine and Its Conversions.

✍ Scribed by A. M. Likhosherstov; V. P. Peresada; V. G. Vinokurov; A. P. Skoldinov


Publisher
John Wiley and Sons
Year
2006
Weight
16 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The synthetic pathway leading to 5,6‐dihydro‐4__H__‐furo[3,2‐__f__]pyrrolo[1,2‐__a__][1,4]diazepines is described in four steps starting from α‐bromophenones __via__ 2‐amino‐3‐furonitriles.

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## Abstract Fused tricyclic 7‐phenyl‐5__H__‐thizolo[5,4‐__e__]pyrrolo[1,2‐__a__][1,4]diazepin‐10(9__H__)one (**10**) was prepared by thermolysis of 2‐phenyl‐4‐(1‐pyrrolylmethyl)thiazole‐5‐carbonyl azide (**9**) in acetic acid. In addition, starting from **10**, 7‐phenyl‐5__H__‐thiazolo [5,4‐__e__][