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Auriophilicity in Polynuclear (Phosphane)gold(I) Thiolates {Me3CS[Au(PPh3)]2}+ BF-4 and {(CH2S)2[Au(PPh3)]3}+ BF-4

✍ Scribed by Sladek, Alexander ;Schmidbaur, Hubert


Publisher
Wiley (John Wiley & Sons)
Year
1995
Tongue
English
Weight
336 KB
Volume
128
Category
Article
ISSN
0009-2940

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Chemistry in Environmentally Benign Medi
✍ Berning, Douglas E. ;Katti, Kattesh V. ;Barnes, Charles L. ;Volkert, Wynn A. πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 473 KB πŸ‘ 1 views

The reactions of water-soluble phosphanes P(CH,OH), (1) and Ph2PCH20H (2) with NaAuC14 in aqueous or alcoholic media, produced the water/alcoholic-soluble Au' complexes [Au(P(CH,OH),),]+ (3) and [Au(Ph2PCH20H):J+ (4) in near quantitative yields. The X-ray structures of 3 and 4, reported in this pape