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Au3SnCuP10 and Au3SnP7: Preparation and Crystal Structures of Au3Sn Heterocluster Polyphosphides.

✍ Scribed by Stefan Lange; Tom Nilges

Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Preparation and Structure of F3As–Au+SbF
Preparation and Structure of F3As–Au+SbF6–, the Structures of Au(CO)2+ and Au(PF3)2+
✍ Ralf KΓΌster; Konrad Seppelt πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 104 KB πŸ‘ 1 views

AuF 3 , Au(SbF 6 ) 2 , or [Au(SbF 6 ) 2 Β΄Au(AuF 4 ) 2 ] react with AsF 3 in HF/SbF 5 under formation of F 3 AsΒ±Au + SbF 6 Β± . This is stable to about 0 Β°C. The crystal structure reveals strong cationic-anionic interactions through one fluorine atom so that a description as F 3 AsΒ±AuΒ±F. . . SbF 5 is