AuF 3 , Au(SbF 6 ) 2 , or [Au(SbF 6 ) 2 ´Au(AuF 4 ) 2 ] react with AsF 3 in HF/SbF 5 under formation of F 3 As±Au + SbF 6 ± . This is stable to about 0 °C. The crystal structure reveals strong cationic-anionic interactions through one fluorine atom so that a description as F 3 As±Au±F. . . SbF 5 is
✦ LIBER ✦
ChemInform Abstract: Preparation and Structure of F3As—Au+SbF6-, the Structure of Au(CO)2+ and Au(PF3)2+.
✍ Scribed by Ralf Kuester; Konrad Seppelt
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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