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Mixed Valent Gold Oxides: Syntheses, Structures, and Properties of Rb5Au3O2, Rb7Au5O2, and Cs7Au5O2

✍ Scribed by Anja-Verena Mudring; Jürgen Nuss; Ulrich Wedig; Martin Jansen

Publisher: Elsevier Science
Year: 2000
Tongue: English
Weight: 408 KB
Volume: 155
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.2000.8881

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The crystal structure of synthetic Rb 2 [B 4 O 5 (OH) 4 ] ' 3.6H 2 O has been established from single-crystal X-ray di4raction data. It crystallizes in the orthorhombic space group Pbcn with a unit cell of dimensions a ‫؍‬ 11.276(5) A s , b ‫؍‬ 13.097(14) A s , c ‫؍‬ 16.751(5) A s ; V ‫؍‬ 2474(3) A